Refine your search:     
Report No.
 - 
Search Results: Records 1-14 displayed on this page of 14
  • 1

Presentation/Publication Type

Initialising ...

Refine

Journal/Book Title

Initialising ...

Meeting title

Initialising ...

First Author

Initialising ...

Keyword

Initialising ...

Language

Initialising ...

Publication Year

Initialising ...

Held year of conference

Initialising ...

Save select records

Journal Articles

Curium(III) species and the coordination states in concentrated LiCl-aqueous solutions studied by time-resolved laser-induced fluorescence spectroscopy

Arisaka, Makoto; Kimura, Takaumi; Nagaishi, Ryuji; Yoshida, Zenko

Journal of Alloys and Compounds, 408-412, p.1307 - 1311, 2006/02

 Times Cited Count:6 Percentile:42.64(Chemistry, Physical)

no abstracts in English

Journal Articles

Structural study of molten lanthanum halides by X-ray diffraction and computer simulation techniques

Okamoto, Yoshihiro; Madden, P. A.*

Journal of Physics and Chemistry of Solids, 66(1), p.448 - 451, 2005/01

The local structure of molten LaCl$$_3$$ has been characterized by the octahedral coordination (LaCl$$_6$$)$$^{3-}$$. It is based on X-ray diffraction (XRD) and Raman spectroscopy results. On the other hand, a different structural image was proposed in the neutron diffraction (ND) and the molecular dynamics (MD) studies. These ND and MD works concluded that a coordination behavior changes with cation size in molten rare earth trichlorides. Thus, they reported the coordination number of Cl$$^-$$ ions around La$$^{3+}$$ ion is 8.2 in the ND work and 7.9 in the MD work. In the present work, XRD measurements of molten LaCl$$_3$$ were performed to investigate the local structure. The coordination number of the 1st La$$^{3+}$$-Cl$$^-$$ pair in molten LaCl$$_3$$ was 7.1 from analysis of the correlation function G(r). The structural change by increasing anion size was examined by the XRD measurement of molten LaBr$$_3$$. The XRD data were nicely reproduced by the MD simulations with polarizable ionic model.

Journal Articles

Pressure-induced sharp coordination change in liquid germanate

Otaka, Osamu*; Arima, Hiroshi*; Fukui, Hiroyuki*; Utsumi, Wataru; Katayama, Yoshinori; Yoshiasa, Akira*

Physical Review Letters, 92(15), p.155506_1 - 155506_4, 2004/04

 Times Cited Count:51 Percentile:84.47(Physics, Multidisciplinary)

Local structures around germanium in liquid germanate have been investigated by means of in situ X-ray absorption measurements up to 9 GPa at 1273 K. Liquid germanate consisting of tetrahedrally coordinated germanium contracts with increasing pressure without significant changes in the local structure up to 2.5 GPa and then shows an abrupt fourfold-to-sixfold coordination change around 3 GPa. The coordination change is completed below 4 GPa where upon a high-density liquid consisting of octahedrally coordinated germanium becomes stable. The GeO$$_{6}$$ octahedron in the high-density liquid is more compressible than that in solids.

Journal Articles

M$"o$ssbauer spectroscopic studies of $$^{237}$$Np in aqueous solutions

Nakada, Masami; Masaki, Nobuyuki; Yamashita, Toshiyuki

Journal of Nuclear Science and Technology, 39(Suppl.3), p.426 - 428, 2002/11

no abstracts in English

Journal Articles

Structural study of lanthanides(III) in aqueous nitrate and chloride solutions by EXAFS

Yaita, Tsuyoshi; Narita, Hirokazu*; Suzuki, Shinichi; Tachimori, Shoichi; Motohashi, Haruhiko; Shiwaku, Hideaki

Journal of Radioanalytical and Nuclear Chemistry, 239(2), p.371 - 375, 1999/00

 Times Cited Count:95 Percentile:98.36(Chemistry, Analytical)

no abstracts in English

Journal Articles

A Correlation between isomer shifts of $$^{237}$$Np Moessbauer spectra and coordination numbers of Np atoms in neptunyl(V) compounds

Saeki, Masakatsu; Nakada, Masami; Nakamoto, Tadahiro*; Yamashita, Toshiyuki; ; Krot, N. N.*

Journal of Radioanalytical and Nuclear Chemistry, 239(2), p.221 - 225, 1999/00

 Times Cited Count:7 Percentile:49.64(Chemistry, Analytical)

no abstracts in English

JAEA Reports

None

PNC TJ1601 98-003, 57 Pages, 1998/03

PNC-TJ1601-98-003.pdf:1.76MB

None

Journal Articles

Luminescence study on determination of the inner-sphere hydration number of Am(III) and Nd(III)

Kimura, Takaumi; Kato, Yoshiharu

Journal of Alloys and Compounds, 271-273, p.867 - 871, 1998/00

 Times Cited Count:67 Percentile:92.53(Chemistry, Physical)

no abstracts in English

Journal Articles

Coordination chemistry of neptunyl(V) compounds by means of Moessbauer spectroscopy

Saeki, Masakatsu; Nakada, Masami; Nakamoto, Tadahiro*; ; Yamashita, Toshiyuki

Journal of Alloys and Compounds, 271-273, p.176 - 179, 1998/00

 Times Cited Count:4 Percentile:39.18(Chemistry, Physical)

no abstracts in English

Journal Articles

$$^{237}$$Np Moessbauer spectroscopic study on pentavalent neptunium glycolate complex

Nakamoto, Tadahiro*; Nakada, Masami; ; Saeki, Masakatsu; Yamashita, Toshiyuki

Journal of Radioanalytical and Nuclear Chemistry, 227(1-2), p.137 - 141, 1998/00

 Times Cited Count:2 Percentile:38.16(Chemistry, Analytical)

no abstracts in English

Journal Articles

Synthesis and properties of some neptunyl(V) phthalates

Saeki, Masakatsu; Nakada, Masami; Yamashita, Toshiyuki; Nakamoto, Tadahiro*; Krot, N. N.*

Radiochimica Acta, 80(2), p.89 - 94, 1998/00

no abstracts in English

Journal Articles

Development of novel extracting-ligand for actinide separation supported by molecular design technique

Tachimori, Shoichi; Yaita, Tsuyoshi; Suzuki, Shinichi

Proc. of Workshop on Long-Lived Radionuclide Chemistry in Nuclear Waste Treatment, p.179 - 188, 1997/00

no abstracts in English

Journal Articles

Pressure-induced structure change of molten KCl

Urakawa, Satoru*; Igawa, Naoki; Umesaki, Norimasa*; Igarashi, Kazuo*; Shimomura, Osamu*; Ono, Hideo

High Pressure Research, 14(4-6), p.375 - 382, 1996/12

 Times Cited Count:6 Percentile:53.11(Physics, Multidisciplinary)

no abstracts in English

Journal Articles

Synergistic extraction of lanthanoids(III) with thenoyltrifluoroacetone and aromatic carboxylic acids and the hydration of the extracted species

*; Kimura, Takaumi; ; *

Anal. Sci. Technol., 8(4), p.499 - 503, 1995/00

no abstracts in English

14 (Records 1-14 displayed on this page)
  • 1